BES include a set of technologies that exploit the ability of certain microorganisms to use electrodes as the electrons acceptors/donors and to catalyze redox reactions in order to promote a flow of electrons. In the present study, we have assessed the possibility to remove Cr(VI) in a biocathodic chamber of a dual-chamber (2C) Microbial Electrolysis Cell (MEC) with cathode as the sole electron donor. The cathode was first put into the anodic compartment of a 2CMicrobial Fuel Cell (MFC) inoculated with sludge from an anaerobic digester. After the acclimation period, the electrode was transferred into the cathodic chamber to work at -300 mV (vs. Standard Hydrogen Electrode - SHE) as the biocathode in a Cr(VI)-reducing MEC with 2000 μg Cr(VI)/L. The acclimation phase in the 2C-MFC allowed to shorten the time for the electroactive-biofilm growth, and to increase the efficiency of the Cr(VI)-reducing MEC. The bioelectrochemical system ensured higher removal efficiency than the pure chemical process.

BIOELECTROCHEMICAL SYSTEM FOR REMOVING HEXAVALENT CHROMIUM FROM WATERS

BERETTA, GABRIELE;A. Mastorgio;E. Sezenna;S. Saponaro
2017-01-01

Abstract

BES include a set of technologies that exploit the ability of certain microorganisms to use electrodes as the electrons acceptors/donors and to catalyze redox reactions in order to promote a flow of electrons. In the present study, we have assessed the possibility to remove Cr(VI) in a biocathodic chamber of a dual-chamber (2C) Microbial Electrolysis Cell (MEC) with cathode as the sole electron donor. The cathode was first put into the anodic compartment of a 2CMicrobial Fuel Cell (MFC) inoculated with sludge from an anaerobic digester. After the acclimation period, the electrode was transferred into the cathodic chamber to work at -300 mV (vs. Standard Hydrogen Electrode - SHE) as the biocathode in a Cr(VI)-reducing MEC with 2000 μg Cr(VI)/L. The acclimation phase in the 2C-MFC allowed to shorten the time for the electroactive-biofilm growth, and to increase the efficiency of the Cr(VI)-reducing MEC. The bioelectrochemical system ensured higher removal efficiency than the pure chemical process.
2017
978-88-8286-324-1
Biocathode, Bioelectrochemical system, Hexavalent chromium reduction.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/1050348
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