Synthetic equivalents, 1,1-bis-hydroxymethyl methylene oxides 7, 18, of trisubstituted carbinol derivatives such as the disymmetrized tetrahedral tris(hydroxymethyl) methanol 17 have been obtained in enantiomerically pure form from (R)-methyl-p-tolylsulfoxide, glycolic acid ethyl ester and diazomethane.
ON THE PREPARATION OF DISYMMETRIZED TRIS(HYDROXYMETHYL) METHANOL EQUIVALENTS
BRAVO, PIERFRANCESCO;FRIGERIO, MASSIMO;MEILLE, STEFANO VALDO;
1995-01-01
Abstract
Synthetic equivalents, 1,1-bis-hydroxymethyl methylene oxides 7, 18, of trisubstituted carbinol derivatives such as the disymmetrized tetrahedral tris(hydroxymethyl) methanol 17 have been obtained in enantiomerically pure form from (R)-methyl-p-tolylsulfoxide, glycolic acid ethyl ester and diazomethane.File in questo prodotto:
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pub067Arnone Methanol equivTetrahedr Asymm 1995.pdf
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