Synchrotron-based UV resonance Raman spectroscopy probes size confinement, termination effects, and anharmonicity of carbon atomic wires

Vibrational and electronic properties and anharmonicity of sp-carbon atomic wires (i.e., polyynes) have been studied using resonance Raman spectroscopy, focusing on the confinement effects connected to their structure (length and termination). We exploited the fine tunability of the synchrotron radiation to resonantly excite short H-, CH3-, and CN-capped carbon atomic wires at their vibronic transitions in the deep UV. We report for the first time the resonance Raman spectra of sizeselected CH3-capped polyynic wires (HCnCH3, n = 8–12) and CN-capped wires (HC6CN and HC12CN). We observed that the degree of π-electron conjugation increases with the wire length and is related to the specific termination. The analysis of multiple quanta Raman overtone bands shows that the anharmonic correction of the vibrational potential energy becomes increasingly relevant as the wire length increases. Finally, studying the vibronic lines of the UV absorption spectra allows the determination of an effective displacement parameter between the minima of the ground and the low-lying excited state, proving that the strong electron-phonon coupling of these systems is sensitive to chain length and termination.