In this work, carbon papers and aerogels based on graphene layers and chitosan were prepared. They were obtained by mixing chitosan (CS) and a high surface area nanosized graphite (HSAG) in water in the presence of acetic acid. HSAG/CS water dispersions were stable for months. High resolution transmission electron microscopy revealed the presence of few graphene layers in water suspensions. Casting or lyophilization of such suspensions led to the preparation of carbon paper and aerogel respectively. In X-ray spectra of both aerogels and carbon paper, peaks due to regular stacks of graphene layers were not detected: graphene with unaltered sp(2) structure was obtained directly from graphite without the use of any chemical reaction. The composites were demonstrated to be electrically conductive, thanks to the graphene. Chitosan thus makes it possible to obtain monolithic carbon aerogels and flexible and free standing graphene papers directly from a nanosized graphite, avoiding oxidation to graphite oxide and successive reduction. Strong interaction between polycationic chitosan and the aromatic substrate appears to be at the origin of the stability of HSAG/CS adducts. Cation-π interaction is hypothesized, also on the basis of XPS findings. This work paves the way for the easy large-scale preparation of carbon papers through a method that has a low environmental impact and is based on a biosourced polymer, graphene and water.

Carbon papers and aerogels based on graphene layers and chitosan: direct preparation from high surface area graphite

Barbera, Vincenzina;Guerra, Silvia;Brambilla, Luigi;Serafini, Andrea;Vitale, Alessandra;Galimberti, Maurizio
2017-01-01

Abstract

In this work, carbon papers and aerogels based on graphene layers and chitosan were prepared. They were obtained by mixing chitosan (CS) and a high surface area nanosized graphite (HSAG) in water in the presence of acetic acid. HSAG/CS water dispersions were stable for months. High resolution transmission electron microscopy revealed the presence of few graphene layers in water suspensions. Casting or lyophilization of such suspensions led to the preparation of carbon paper and aerogel respectively. In X-ray spectra of both aerogels and carbon paper, peaks due to regular stacks of graphene layers were not detected: graphene with unaltered sp(2) structure was obtained directly from graphite without the use of any chemical reaction. The composites were demonstrated to be electrically conductive, thanks to the graphene. Chitosan thus makes it possible to obtain monolithic carbon aerogels and flexible and free standing graphene papers directly from a nanosized graphite, avoiding oxidation to graphite oxide and successive reduction. Strong interaction between polycationic chitosan and the aromatic substrate appears to be at the origin of the stability of HSAG/CS adducts. Cation-π interaction is hypothesized, also on the basis of XPS findings. This work paves the way for the easy large-scale preparation of carbon papers through a method that has a low environmental impact and is based on a biosourced polymer, graphene and water.
2017
chitosan, graphene, carbon paper, monolithic aerogel
File in questo prodotto:
File Dimensione Formato  
acs.biomac.7b01026.pdf

Accesso riservato

Descrizione: Articolo principale
: Post-Print (DRAFT o Author’s Accepted Manuscript-AAM)
Dimensione 2.74 MB
Formato Adobe PDF
2.74 MB Adobe PDF   Visualizza/Apri
bm7b01026_si_007.pdf

Accesso riservato

Descrizione: Supporting Information
: Altro materiale allegato
Dimensione 1.09 MB
Formato Adobe PDF
1.09 MB Adobe PDF   Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/1036082
Citazioni
  • ???jsp.display-item.citation.pmc??? 6
  • Scopus 19
  • ???jsp.display-item.citation.isi??? 18
social impact