Six halogen-bonded cocrystals involving aromatic donors have been studied by far-IR spectroscopy. Characteristic redshift and intensity enhancement of the C-I stretching band have been observed, which provided a distinct signature of the halogen bond involving iodopentafluorobenzene.

Characteristic redshift and intensity enhancement as far-IR fingerprints of the halogen bond involving aromatic donors

VASYLYEVA, VIRA;CATALANO, LUCA;METRANGOLO, PIERANGELO;RESNATI, GIUSEPPE
2016

Abstract

Six halogen-bonded cocrystals involving aromatic donors have been studied by far-IR spectroscopy. Characteristic redshift and intensity enhancement of the C-I stretching band have been observed, which provided a distinct signature of the halogen bond involving iodopentafluorobenzene.
CRYSTENGCOMM
Chemistry (all); Materials Science (all); Condensed Matter Physics
CHARGE-TRANSFER COMPLEXES; PERFLUORO-ORGANO BROMIDES; SUPRAMOLECULAR MATERIALS; INFRARED-ABSORPTION; SIGMA-HOLE; IODINE; PYRIDINE; BENZENE; SPECTRA; BASES
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11311/996050
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