Particle settling is a pervasive process in nature, and centrifugation is a versatile separation technique. Yet, the results of settling and ultracentrifugation experiments often appear to contradict the very law on which they are based: Archimedes' principle - arguably, the oldest physical law. The purpose of this paper is delving into the very roots of the concept of buoyancy by means of a combined experimental-theoretical study on sedimentation profiles in colloidal mixtures. Our analysis shows that the standard Archimedes' principle is only a limiting approximation, valid for mesoscopic particles settling in a molecular fluid, and we provide a general expression for the actual buoyancy force. This "Generalized Archimedes' Principle" accounts for unexpected effects, such as denser particles floating on top of a lighter fluid, which in fact we observe in our experiments.

What buoyancy really is. A generalized Archimedes' principle for sedimentation and ultracentrifugation

PIAZZA, ROBERTO;BUZZACCARO, STEFANO;SECCHI, ELEONORA;
2012

Abstract

Particle settling is a pervasive process in nature, and centrifugation is a versatile separation technique. Yet, the results of settling and ultracentrifugation experiments often appear to contradict the very law on which they are based: Archimedes' principle - arguably, the oldest physical law. The purpose of this paper is delving into the very roots of the concept of buoyancy by means of a combined experimental-theoretical study on sedimentation profiles in colloidal mixtures. Our analysis shows that the standard Archimedes' principle is only a limiting approximation, valid for mesoscopic particles settling in a molecular fluid, and we provide a general expression for the actual buoyancy force. This "Generalized Archimedes' Principle" accounts for unexpected effects, such as denser particles floating on top of a lighter fluid, which in fact we observe in our experiments.
BUOYANCY; SIZE SEPARATION; CENTRIFUGATION; FRACTIONATION; COLLOIDS
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11311/686612
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