Orthogonal self-assembly of an open organic framework showing 2D channels has been obtained by combining hydrogen and halogen bonding. The framework is able to host various guest molecules with a diverse set of steric demands and substitution patterns, and survives single-crystal-to-single-crystal guest exchanges from liquid and gas phases.
Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels
J. Martí Rujas;COLOMBO, LUCA;TERRANEO, GIANCARLO;METRANGOLO, PIERANGELO;PILATI, TULLIO MARIA;RESNATI, GIUSEPPE
2012-01-01
Abstract
Orthogonal self-assembly of an open organic framework showing 2D channels has been obtained by combining hydrogen and halogen bonding. The framework is able to host various guest molecules with a diverse set of steric demands and substitution patterns, and survives single-crystal-to-single-crystal guest exchanges from liquid and gas phases.File in questo prodotto:
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