Alkylation of H2O-sol. ketones by lipophilic alkenes was efficiently initiated by the Ag+-catalyzed decompn. of S2O82- in H2O. E.g., a refluxing mixt. of aq. AgNO3, Me2CO, and 1-octene was treated by addn. of aq. Na2S2O8 during 6 h under N and further refluxed for 2 h to give 65% MeCO(CH2)8Me
Addition of ketones to olefins by silver cation-catalyzed decomposition of peroxydisulfat
CITTERIO, ATTILIO;
1983-01-01
Abstract
Alkylation of H2O-sol. ketones by lipophilic alkenes was efficiently initiated by the Ag+-catalyzed decompn. of S2O82- in H2O. E.g., a refluxing mixt. of aq. AgNO3, Me2CO, and 1-octene was treated by addn. of aq. Na2S2O8 during 6 h under N and further refluxed for 2 h to give 65% MeCO(CH2)8MeFile in questo prodotto:
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