Side-chain oxidn. of PhCH(CO2R) (R = alkyl) and its derivs. by Mn(OAc)3 in AcOH, C6H6, and hexane, alone or in the presence of O or halide and pseudohalide ions (N3-, thiocyanate, Br-, Cl-) gives PhCR1(CO2R) (R1 = OAc, N3, thiocyanato, Br, Cl). The products obtained depend on the structure of the starting malonate and the reaction conditions
Side-chain oxidation of dialkyl arylmalonates by manganese(III) acetate
CITTERIO, ATTILIO;
1988-01-01
Abstract
Side-chain oxidn. of PhCH(CO2R) (R = alkyl) and its derivs. by Mn(OAc)3 in AcOH, C6H6, and hexane, alone or in the presence of O or halide and pseudohalide ions (N3-, thiocyanate, Br-, Cl-) gives PhCR1(CO2R) (R1 = OAc, N3, thiocyanato, Br, Cl). The products obtained depend on the structure of the starting malonate and the reaction conditionsFile in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
