Iron (III) salts (perchlorate and nitrate nonahydrate) in acetonitrile or acetic anhydride at 0–50°C oxidize the α-position of malonic esters efficiently via the corresponding radicals. In the presence of olefins and aromatics, inter- and intramolecular free radical chain or oxidative additions are observed
Oxidative deprotonation of carbonyl compounds by iron(III) salts
CITTERIO, ATTILIO;SEBASTIANO, ROBERTO;
1989-01-01
Abstract
Iron (III) salts (perchlorate and nitrate nonahydrate) in acetonitrile or acetic anhydride at 0–50°C oxidize the α-position of malonic esters efficiently via the corresponding radicals. In the presence of olefins and aromatics, inter- and intramolecular free radical chain or oxidative additions are observedFile in questo prodotto:
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