Two epimeric 1,3,4-trideoxy-3-fluoronojirimycins are obtained through a total asymmetric synthesis starting from a non-carbohydrate precursor; two key-steps of the synthetic sequence are an intramolecular aminomercuration reaction and an oxidative demercuration process.
Asymmetric synthesis of fluorinated analogues of 1-deoxynojirimycin
BRAVO, PIERFRANCESCO;RESNATI, GIUSEPPE
1993-01-01
Abstract
Two epimeric 1,3,4-trideoxy-3-fluoronojirimycins are obtained through a total asymmetric synthesis starting from a non-carbohydrate precursor; two key-steps of the synthetic sequence are an intramolecular aminomercuration reaction and an oxidative demercuration process.File in questo prodotto:
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