Polyfluoroalkoxy trimethylsilanes RfCH2OSi(CH3)3 (from the alcohols RfCH2OH and HMDS), react with Ph3PICl (from ICl and Ph3P) eliminating (CH3)3SiCl. Pyrolysis of the residues gives Ph3PO and pure iodides RfCH2I.

1-Iodo-polyfluoroalkanes from polyfluoroalkoxy trimethylsilanes and iodochloro triphenylphosphorane

RESNATI, GIUSEPPE
1994-01-01

Abstract

Polyfluoroalkoxy trimethylsilanes RfCH2OSi(CH3)3 (from the alcohols RfCH2OH and HMDS), react with Ph3PICl (from ICl and Ph3P) eliminating (CH3)3SiCl. Pyrolysis of the residues gives Ph3PO and pure iodides RfCH2I.
1994
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/655562
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