Hierarchical and comparative kinetic modeling of laminar flame speeds of hydrocarbon and oxygenated fuels

The primary objective of the present endeavor is to collect, consolidate, and review the vast amount of experimental data on the laminar flame speeds of hydrocarbon and oxygenated fuels that have been reported in recent years, analyze them by using a detailed kinetic mechanism for the pyrolysis and combustion of a large variety of fuels at high temperature conditions, and thereby identify aspects of the mechanism that require further revision. The review and assessment was hierarchically conducted, in the sequence of the foundational C0eC4 species; the reference fuels of alkanes (n-heptane, iso-octane, ndecane, n-dodecane), cyclo-alkanes (cyclohexane and methyl-cyclo-hexane) and the aromatics (benzene, toluene, xylene and ethylbenzene); and the oxygenated fuels of alcohols, C3H6O isomers, ethers (dimethyl ether and ethyl tertiary butyl ether), and methyl esters up to ethyl decanoate. Mixtures of some of these fuels, including those with hydrogen, were also considered. The comprehensive nature of the present mechanism and effort is emphasized.