A free radical multicomponent reaction mediated by an acidic TiCl4-Zn/H2O2 system allows the assembly of an amine, a ketone, and formamide in one pot, affording instant access to quaternary alpha-amino acid derivatives.
Free-Radical Addition to Ketimines Generated In Situ. New One- Pot Synthesis of Quaternary alpha-Aminoamides Promoted by a H2O2/TiCl4-Zn/HCONH2 System
PASTORI, NADIA;GRECO, COSIMINA;CLERICI, ANGELO;PUNTA, CARLO;PORTA, OMBRETTA
2010-01-01
Abstract
A free radical multicomponent reaction mediated by an acidic TiCl4-Zn/H2O2 system allows the assembly of an amine, a ketone, and formamide in one pot, affording instant access to quaternary alpha-amino acid derivatives.File in questo prodotto:
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