Effect of pressure on the PVT behaviour of iPP as revealed by dilatometric measurements

Isotactic Poly-Propylene samples, previously prepared under known conditions of pressure and cooling rate by means of a Special apparatus designed and setup by the authors, were subjected to several isobaric runs at low cooling and heating rate in a confining fluid dilatometer (by GNOMIX). The effect of the previous thermo-mechanical histories and the effect of pressure in the dilatometry on specific volume of the samples was studied. Results show that the initial specific volume depends upon the previous thermo-mechanical histories, which however cancels out after the first heating run. Moreover the reported dilatometric experimental data Support the evidence that an increase of pressure at a constant cooling rate acts as an increase of cooling rate at a constant pressure.