Viscoelasticity and shear yielding in amorphous glassy polymers

In the present work, the effect of viscoelasticity on the yield behaviour of a polycarbonate, PC, was studied and the identification of a yield criterion which takes into account the effects of the mechanical history on the onset of plastic strain, was attempted. The attention was focused on the shear yielding plastic deformation process and different loading histories were performed under uniaxial compression: constant strain rate at different rates, stress relaxation at different applied strain levels, creep under different stress levels. Some tests were also carried out under shear loading, in which the hydrostatic stress component is equal to zero and its effect on the yield onset can be considered. For the definition of a yield criterion, different quantities, some already proposed in an analogous work on a styrene- acrylonitrile copolymer (SAN), were considered and determined at yield onset for each of the applied loading histories. The results obtained in this work show that the relative ratios of the viscoelastic strain over the overall strain and of viscoelastic energy over the deformation work are fairly constant irrespective of both loading history and stress state. The re-elaboration of the data previously obtained on SAN is consistent with these results. Discussing the experimental data, differences between the mechanical behaviour of the two glassy polymers were pointed out and a more difficult activation of the plastic deformation process of PC than SAN was generally observed.