On the surface: Mixed monolayers, which on flat surfaces phase-separate into randomly shaped domains, spontaneously form ordered rings of alternating composition when assembled around the core of a monolayer-protected gold nanoparticle (see figure). It is shown that it is possible to use infrared spectroscopy, a simple and common technique, to prove the existence of these phase-separated domains on nanoparticles.

Phase Separation on Mixed-Monolayer-Protected Metal Nanoparticles: A Study by Infrared Spectroscopy and Scanning Tunneling Microscopy

CENTRONE, ANDREA;ZERBI, GIUSEPPE
2007-01-01

Abstract

On the surface: Mixed monolayers, which on flat surfaces phase-separate into randomly shaped domains, spontaneously form ordered rings of alternating composition when assembled around the core of a monolayer-protected gold nanoparticle (see figure). It is shown that it is possible to use infrared spectroscopy, a simple and common technique, to prove the existence of these phase-separated domains on nanoparticles.
2007
IR spectroscopy; monolayers; nanoparticles; phase separation; scanning tunneling microscopy
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/552343
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