Attempts to synthesize a phenanthroline palladium(0) complex with an eta 2-coordinated nitrosoarene starting from a palladium(ii) precursor and the corresponding aryl hydroxylamine afforded instead apparent palladium(i) metallacyclic complexes that, on a closer inspection, were proven to be Pd(ii) complexes with a new kind of radical-anionic nitrosoarene ligand.
A non-innocent radical-anionic nitrosoarene ligand regularizes a formal palladium(I) complex to palladium(II)
Macchi, Piero;
2026-01-01
Abstract
Attempts to synthesize a phenanthroline palladium(0) complex with an eta 2-coordinated nitrosoarene starting from a palladium(ii) precursor and the corresponding aryl hydroxylamine afforded instead apparent palladium(i) metallacyclic complexes that, on a closer inspection, were proven to be Pd(ii) complexes with a new kind of radical-anionic nitrosoarene ligand.File in questo prodotto:
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