Progress in the Development of a W-based Corrosion Barrier for ENEA Liquid Sn-based Divertor Design

Experimental research was conducted to develop a corrosion barrier for protecting the copper-chromium-zirconium (CuCrZr) and stainless steel components of future liquid tin divertors. W-based coatings with tailored properties were deposited on planar metallic samples by high power impulse magnetron sputtering (HiPIMS), optimizing the deposition parameters to enhance mechanical properties and improve corrosion resistance. A validation experimental campaign was carried out based on conditions expected in the ENEA liquid metal divertor design. To identify the highest-performing coating, coated samples were exposed to a static droplet of liquid tin at C for up to 600 min, followed by post-mortem characterization. The results indicate that tin corrosion is significantly less concerning towards steel and can be effectively prevented under these operating conditions through the developed coatings. On CuCrZr substrates, pure-W coatings demonstrated insufficient corrosion protection and reliability issues, leading to mechanical failure of the barrier. The experiments underlined the importance of substrate preparation and surface defects on corrosion barrier properties. In contrast, W-Al coatings were able to successfully and reliably prevent liquid tin corrosion, indicating that low-crystallinity and amorphous materials are more suitable as corrosion barriers for liquid tin divertor applications.