A process for decontaminating a contaminated organic material comprising or consisting of ion-exchange resins embedding toxic and/or radioactive pollutant ions comprising the following steps:a) subjecting said ion-exchange resin to a mineralization process in water by adding an oxidizer in the presence of catalysts based on iron sulphate copper sulphate or mixtures thereof;b) recovering contaminated inorganic compounds;c) preparing a stable matrix for the confinement and embedding of contaminated inorganic materials recovered in stage b)characterized in thatstage b) comprises the following stages:b1) adding the aqueous mixture from stage a) with an aqueous solution of an alkali metal hydroxide until a pH value of or above 9 preferably of between 9 and 11 still more preferably of 10 is reached for facilitating a precipitation and/or co-precipitation of said inorganic mineral compounds containing said toxic and/or radioactive metal ions;b2) adding the suspension obtained in stage b1) with zeolites in order to embed the residual ions of several toxic and/or radioactive metals more preferably those of cesium the compounds thereof being soluble at the alkaline pH of the solution; and said stage b2) being performed under vigorous and constant mixing subsequently to stage b1);b3) separating the solid residue from the reaction mixture from stage b2) by filtration or subsequent decanting of the suspension and subsequent centrifugation of the decanted mixture.

Integrated process for disposal of organic matrices

Mariani, Mario;Mossini, Eros;Galluccio, Francesco;Santi, Andrea
2024-01-01

Abstract

A process for decontaminating a contaminated organic material comprising or consisting of ion-exchange resins embedding toxic and/or radioactive pollutant ions comprising the following steps:a) subjecting said ion-exchange resin to a mineralization process in water by adding an oxidizer in the presence of catalysts based on iron sulphate copper sulphate or mixtures thereof;b) recovering contaminated inorganic compounds;c) preparing a stable matrix for the confinement and embedding of contaminated inorganic materials recovered in stage b)characterized in thatstage b) comprises the following stages:b1) adding the aqueous mixture from stage a) with an aqueous solution of an alkali metal hydroxide until a pH value of or above 9 preferably of between 9 and 11 still more preferably of 10 is reached for facilitating a precipitation and/or co-precipitation of said inorganic mineral compounds containing said toxic and/or radioactive metal ions;b2) adding the suspension obtained in stage b1) with zeolites in order to embed the residual ions of several toxic and/or radioactive metals more preferably those of cesium the compounds thereof being soluble at the alkaline pH of the solution; and said stage b2) being performed under vigorous and constant mixing subsequently to stage b1);b3) separating the solid residue from the reaction mixture from stage b2) by filtration or subsequent decanting of the suspension and subsequent centrifugation of the decanted mixture.
2024
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/1290107
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