The extraction of volatile fatty acids (VFAs) from an aqueous solution derived by fermentation of food waste is a key challenge in the context of the circular economy, thanks to their high economic and environmental impact due to their wide-ranging use in various industrial fields. In this work, we compared two different extraction methods: one novel and one classical. Firstly, iron oxide nanoparticles of around 10 nm were prepared and used as they are or functionalised using (3-Aminopropyl)triethoxysilane) (APTES) molecules, adipic acid and oleic acid. This was compared with a traditional industrial method (liquid-liquid extraction) that can guarantee high extraction of VFAs with high reproducibility. Indeed the use of dichloromethane, hexane, methyl tert-butyl ether and oleic acid presented extraction values of up to 30 % while iron oxide NPs showed results with low reproducibility. The comparison demonstrated the use of oleic acid as a promising solvent for liquid-liquid extraction of VFAs.

On the extraction of volatile fatty acids from food waste mixtures: comparison between the use of liquid-liquid and magnetic nanoparticle technologies

Lacroce E.;Rossi F.;Gelosa S.;Busini V.;Masi M.
2024-01-01

Abstract

The extraction of volatile fatty acids (VFAs) from an aqueous solution derived by fermentation of food waste is a key challenge in the context of the circular economy, thanks to their high economic and environmental impact due to their wide-ranging use in various industrial fields. In this work, we compared two different extraction methods: one novel and one classical. Firstly, iron oxide nanoparticles of around 10 nm were prepared and used as they are or functionalised using (3-Aminopropyl)triethoxysilane) (APTES) molecules, adipic acid and oleic acid. This was compared with a traditional industrial method (liquid-liquid extraction) that can guarantee high extraction of VFAs with high reproducibility. Indeed the use of dichloromethane, hexane, methyl tert-butyl ether and oleic acid presented extraction values of up to 30 % while iron oxide NPs showed results with low reproducibility. The comparison demonstrated the use of oleic acid as a promising solvent for liquid-liquid extraction of VFAs.
2024
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/1267822
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