Organic Rankine cycle-ejector heat pump hybrid system using low GWP zeotropic mixtures for trigeneration application

This paper presents a comprehensive study focused on improving the thermal efficiency and performance of an organic Rankine cycle (ORC) combined with an ejector heat pump (EHP) for trigeneration application. The utilization of zeotropic mixtures with low global warming potential (GWP) was proposed as a solution to address the inherent inefficiencies of the ORC at low-temperature heat sources and to enhance the coefficient of performance (COP) of the ejector refrigeration cycle. A thermodynamic model was developed to predict system performance, utilizing low-temperature heat sources such as solar or geothermal energy, along with zeotropic mixtures. The model was validated with the available literature data, demonstrating very good agreement. Five zeotropic fluid mixtures were preliminary studied, and the optimal mass fractions identified. Detailed investigations were then carried out for two of these mixtures, R1233zd(E)/propane and butane/propane, which exhibit low GWP and ozone depletion potential (ODP). The influence of generator temperature and entrainment ratio on system efficiency metrics, exergy, and COP were evaluated for these mixtures. Conclusions are drawn based on the two optimized zeotropic mixtures for maximum thermal efficiency. For R1233zd(E)/propane mixture with mass fractions 0.75/0.25 and butane/propane mixture with mass fractions 0.5/0.5 at generator temperature of 75 °C and entrainment ratio of 0.5, the systems achieved a heating capacity of 1607.9 kW and 2847.9 kW, a cooling capacity of 1037.5 kW and 1280.3 kW, and a net power output of 59.2 kW and 136.3 kW. Other related performance and efficiency parameters are included in the paper. These findings indicate the feasibility of utilizing these systems for trigeneration application. Additionally, a comparative analysis with a regenerative ORC highlighted the ORC-EHP hybrid system's advantages, including enhanced heating efficiency, cooling capacity, and overall COP. This research contributes valuable insights to advance the efficiency and sustainability of combined cooling, heat, and power systems, fostering the progression of innovative energy solutions.