Matere bonds (MaB) to rhenium in a set of organic perrhenates are probed via Re-185/187 solid-state NMR in applied magnetic fields of up to 35.2 T, and via Re-185/187 NQR. Re-185/187 quadrupolar couplings distinguish between MaB samples and control samples, and their precise values are governed by shear strain of the ReO4- anions.
Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy
Calabrese, Miriam;Pizzi, Andrea;Resnati, Giuseppe;
2023-01-01
Abstract
Matere bonds (MaB) to rhenium in a set of organic perrhenates are probed via Re-185/187 solid-state NMR in applied magnetic fields of up to 35.2 T, and via Re-185/187 NQR. Re-185/187 quadrupolar couplings distinguish between MaB samples and control samples, and their precise values are governed by shear strain of the ReO4- anions.File in questo prodotto:
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