Hydrophobic non-ionic eutectogels (HEG) are prepared for the first time from hydrophobic non-ionic (type V) eutectic solvents (HES) in a simple one-pot procedure with a low-cost low molecular weight gelator. Stable and homogeneous gels were obtained in a matter of minutes at a very low loading, with a preparation process ranked as “excellent” in the EcoScale metrics. We illustrate that the liquid-like nature of the hydrophobic mixture is retained upon gelation. From a physicochemical viewpoint, the major finding is the unexpected increase of the diffusive motion of the components in the HEG compared to pure HES. In one case, two populations corresponding to fast and slow diffusion components have been detected. These features of HEG overall open up new horizons toward technological applications requiring solid-like, yet mobile systems, and could promote their usage on a large scale.
Hydrophobic eutectogels: a new outfit for non-ionic eutectic solvents
G. de Araujo Lima e Souza;M. E. Di Pietro;V. Vanoli;F. Briatico Vangosa;F. Castiglione;A. Mele
2023-01-01
Abstract
Hydrophobic non-ionic eutectogels (HEG) are prepared for the first time from hydrophobic non-ionic (type V) eutectic solvents (HES) in a simple one-pot procedure with a low-cost low molecular weight gelator. Stable and homogeneous gels were obtained in a matter of minutes at a very low loading, with a preparation process ranked as “excellent” in the EcoScale metrics. We illustrate that the liquid-like nature of the hydrophobic mixture is retained upon gelation. From a physicochemical viewpoint, the major finding is the unexpected increase of the diffusive motion of the components in the HEG compared to pure HES. In one case, two populations corresponding to fast and slow diffusion components have been detected. These features of HEG overall open up new horizons toward technological applications requiring solid-like, yet mobile systems, and could promote their usage on a large scale.File | Dimensione | Formato | |
---|---|---|---|
240_Materials Today Chemistry_eutectogels.pdf
Accesso riservato
Descrizione: pubblicato
:
Publisher’s version
Dimensione
1.51 MB
Formato
Adobe PDF
|
1.51 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.