This paper shows that, for a large number of particles and for distinguishable and noninteracting identical particles, convergence to equiprobability of the W microstates of the famous Boltzmann–Planck entropy formula S = k log(W) is proved by the Shannon–McMillan theorem, a cornerstone of information theory. This result further strengthens the link between information theory and statistical mechanics.

The Shannon–McMillan Theorem Proves Convergence to Equiprobability of Boltzmann’s Microstates

A. Spalvieri
2021-01-01

Abstract

This paper shows that, for a large number of particles and for distinguishable and noninteracting identical particles, convergence to equiprobability of the W microstates of the famous Boltzmann–Planck entropy formula S = k log(W) is proved by the Shannon–McMillan theorem, a cornerstone of information theory. This result further strengthens the link between information theory and statistical mechanics.
2021
Boltzmann–Planck entropy formula; Shannon–McMillan theorem, equiprobability of microstates
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/1183654
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