Nonporous hybrid metal-organic materials self-assembled by a ditopic organic ligand and copper(ii) have shown a dynamic behavior by releasing and trapping HCl. The solid-state process involves major structural reorganizations comprising cleavage and formation of coordination and covalent chemical bonds by mechanochemical reactions, heating reactions or chemisorption. Single crystal X-ray diffraction, powder X-ray diffraction and TGA in combination with DFT specific for solid-state systems have been used to study the solid-state reactivity.

Dynamic behaviour in nonporous hybrid metal–organic materials via mechanochemical and gas–solid reactions

Famulari, Antonino;MARTI RUJAS, JAVIER
2018

Abstract

Nonporous hybrid metal-organic materials self-assembled by a ditopic organic ligand and copper(ii) have shown a dynamic behavior by releasing and trapping HCl. The solid-state process involves major structural reorganizations comprising cleavage and formation of coordination and covalent chemical bonds by mechanochemical reactions, heating reactions or chemisorption. Single crystal X-ray diffraction, powder X-ray diffraction and TGA in combination with DFT specific for solid-state systems have been used to study the solid-state reactivity.
File in questo prodotto:
File Dimensione Formato  
c8ce01287c.pdf

Accesso riservato

: Publisher’s version
Dimensione 2.37 MB
Formato Adobe PDF
2.37 MB Adobe PDF   Visualizza/Apri
c8ce01287c1.pdf

Accesso riservato

: Publisher’s version
Dimensione 2.02 MB
Formato Adobe PDF
2.02 MB Adobe PDF   Visualizza/Apri
c8ce01287c2.cif

Accesso riservato

: Publisher’s version
Dimensione 86.33 kB
Formato cif
86.33 kB cif   Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/1072795
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 8
  • ???jsp.display-item.citation.isi??? 8
social impact