Pt(S,S)-bdpp(R)I (bdpp = 2,4-bis(diphenylphosphino)pentane; R = Me, Ph, Bz, 2-Tioph) complexes were formed in alkyl/aryl ligand - iodide ligand-exchange reactions by reacting the corresponding Pt(S,S)-bdppR2complexes with methyl iodide. The Pt(S,S)-bdpp(Me)I complex was isolated and fully characterised. The influence of the X ligand on the platinum-bdpp chelate conformation was investigated in Pt(S,S)-bdpp(X)I (X = I, SnCl3, Me) complex series by means of X-ray crystallography. © 2006 Elsevier B.V. All rights reserved.
Synthesis of platinum-iodo-alkyl/aryl complexes in ligand-exchange reactions: Determination of the structure of Pt(S,S)-bdpp(X)I complexes (X = Me, I) by X-ray crystallography
Macchi, Piero;
2006-01-01
Abstract
Pt(S,S)-bdpp(R)I (bdpp = 2,4-bis(diphenylphosphino)pentane; R = Me, Ph, Bz, 2-Tioph) complexes were formed in alkyl/aryl ligand - iodide ligand-exchange reactions by reacting the corresponding Pt(S,S)-bdppR2complexes with methyl iodide. The Pt(S,S)-bdpp(Me)I complex was isolated and fully characterised. The influence of the X ligand on the platinum-bdpp chelate conformation was investigated in Pt(S,S)-bdpp(X)I (X = I, SnCl3, Me) complex series by means of X-ray crystallography. © 2006 Elsevier B.V. All rights reserved.File in questo prodotto:
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