The complex Ru(TPP)(NAr)2inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides. © 2009 The Royal Society of Chemistry.
The key intermediate in the amination of saturated C-H bonds: Synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)2(Ar = 3,5-(CF3)2C6H3)
MacChi, Piero;
2009-01-01
Abstract
The complex Ru(TPP)(NAr)2inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides. © 2009 The Royal Society of Chemistry.File in questo prodotto:
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