The intermediacy of CO/NO substitution in the condensation of [Pt19(CO)22]4-into [Pt38(CO)44]2-(structure shown) has been demonstrated. Two high-nuclearity carbonyl metal clusters, including one with an unprecedented nitrosyl ligand, have been synthesized and structurally characterized.
[Pt19(CO)21(NO)]3-and [Pt38(CO)44]2-: Nitrosyl bending through intramolecular electron transfer as an intermediate step in the nucleation process from polydecker to ccp platinum carbonyl clusters
Macchi, Piero;
1999-01-01
Abstract
The intermediacy of CO/NO substitution in the condensation of [Pt19(CO)22]4-into [Pt38(CO)44]2-(structure shown) has been demonstrated. Two high-nuclearity carbonyl metal clusters, including one with an unprecedented nitrosyl ligand, have been synthesized and structurally characterized.File in questo prodotto:
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