Tetrairidium carbonyl clusters are potentially useful connectors for multidimensional functionalized frameworks with organic bis-phosphines as linkers. The reaction of Ir4(CO)12and 1,4-bis(diphenylphosphinomethyl)benzene produces an oligomeric cyclic structure, made of 4 connectors and 6 linkers, a possible intermediate in the formation of three dimensional networks. © The Royal Society of Chemistry 2010.
Four tetrairidium carbonyl clusters linked by six diphosphino ligands: Synthesis and X-ray structure of [Ir4(CO)94(dppmb)6] (dppmb = 1,4-bis(diphenylphosphinomethyl) benzene
Peli, Giulia;Daghetta, Matteo;MacChi, Piero;
2010-01-01
Abstract
Tetrairidium carbonyl clusters are potentially useful connectors for multidimensional functionalized frameworks with organic bis-phosphines as linkers. The reaction of Ir4(CO)12and 1,4-bis(diphenylphosphinomethyl)benzene produces an oligomeric cyclic structure, made of 4 connectors and 6 linkers, a possible intermediate in the formation of three dimensional networks. © The Royal Society of Chemistry 2010.File in questo prodotto:
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