Actinide-lanthanide co-extraction by rigidified diglycolamides

Within the actinide and lanthanide co-extraction strategy, three rigidified diglycolamides, namely 2,6-bis (N-dodecyl-carboxamide)-4-oxo-4H-pyran (1), 2,6-bis-[N-(4-tert-butylphenyl)carboxamide]-4-oxo-4H-pyran (2), 2,6-​bis[(N-docecyl-N-methyl)carboxamide]-​4-methoxy-​tetrahydro-pyran (3), were synthesized. Moreover, the effect of structural rigidification on Am(III) and Eu(III) extraction under different conditions was investigated. The carboxamide extractant 3 resembles the extracting behavior of N,N,N′,N′‐tetraoctyl diglycolamide (TODGA) in terms of efficiency and affinity within the lanthanide family, together with fast kinetics and satisfactory cation back-extraction. The presence of 1-octanol in the diluent mixture strongly affects the ligand stability. Moreover, despite the low extraction efficiency showed by 1 and 2, all the three ligands exhibit a higher affinity for Am with respect to TODGA, resulting in a lower lanthanide/Americium separation factor, of around 4 for ligand 3 and close to 1 for ligands 1 and 2.