Silver catalyzed peroxydisulphate oxidation of acetone in the presence of olefins and protonated heteroaromatic bases leads to compound I via addition of acetonyl radical to the olefin and scavenging of the resulting radical adduct by the aromatic base. © 1982.
Polar effects in free-radical reactions. A new type of homolytic aromatic alkylation by silver catalyzed oxidation of acetone by peroxydisulphate in the presence of olefins
Citterio, Attilio;Minisci, Francesco
1982-01-01
Abstract
Silver catalyzed peroxydisulphate oxidation of acetone in the presence of olefins and protonated heteroaromatic bases leads to compound I via addition of acetonyl radical to the olefin and scavenging of the resulting radical adduct by the aromatic base. © 1982.File in questo prodotto:
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44_Tetahedron Letters 1982 s0040-4039%2800%2985902-x.pdf
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