Silver catalyzed peroxydisulphate oxidation of acetone in the presence of olefins and protonated heteroaromatic bases leads to compound I via addition of acetonyl radical to the olefin and scavenging of the resulting radical adduct by the aromatic base. © 1982.

Polar effects in free-radical reactions. A new type of homolytic aromatic alkylation by silver catalyzed oxidation of acetone by peroxydisulphate in the presence of olefins

Citterio, Attilio;Minisci, Francesco
1982-01-01

Abstract

Silver catalyzed peroxydisulphate oxidation of acetone in the presence of olefins and protonated heteroaromatic bases leads to compound I via addition of acetonyl radical to the olefin and scavenging of the resulting radical adduct by the aromatic base. © 1982.
1982
Organic Chemistry; Free Radicals; Oxidation; Peroxidisulfate; Chain Reaction
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/1047412
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