A new synthesis of gamma-lactones by peroxydisulfate oxidation of aliphatic carboxylic acids in the presence of olefins is described. From a synthetic point of view the method is an alternative to those based on the oxidation of the same acids by metal ions, such as Mn(III), Ce(IV), and Pb(IV), with the advantage of using a more readily available and less expensive oxidant.
Electron-Transfer Processes. New Synthesis of γ-Lactones by Peroxydisulfate Oxidation of Aliphatic Carboxylic Acids in the Presence of Olefins
Citterio, Attilio
1981-01-01
Abstract
A new synthesis of gamma-lactones by peroxydisulfate oxidation of aliphatic carboxylic acids in the presence of olefins is described. From a synthetic point of view the method is an alternative to those based on the oxidation of the same acids by metal ions, such as Mn(III), Ce(IV), and Pb(IV), with the advantage of using a more readily available and less expensive oxidant.File in questo prodotto:
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