A new synthesis of γ-lactones by peroxydisulfate oxidation of isopropylbenzenes is described. Evidence concerning the free-radical mechanism is reported; the intermediate formation of alkyl and benzyl radicals is evidenced by trapping them with quinoxaline. The role of the iron catalyst is discussed. © 1980.
Electron-transfer processes. New synthesis of γ-lactones by peroxydisulfate oxidation of isopropylbenzenes and aliphatic carboxylic acids
Citterio, Attilio;Minisci, Francesco
1980-01-01
Abstract
A new synthesis of γ-lactones by peroxydisulfate oxidation of isopropylbenzenes is described. Evidence concerning the free-radical mechanism is reported; the intermediate formation of alkyl and benzyl radicals is evidenced by trapping them with quinoxaline. The role of the iron catalyst is discussed. © 1980.File in questo prodotto:
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