By using a kinetic model based on the irreversible isomerizaticn of 5-hexenyl radical, the absolute rate constants for free-radical addition to 1,4-benzcquincne was determined (ka = (2.0 + 0.7).107 M-1 sec-1 at 69°C).
Nucleophilic character of alkyl radicals. Rate constant and new methods of homolytic alkylation of 1,4-benzoquinone
Citterio, Attilio
1978-01-01
Abstract
By using a kinetic model based on the irreversible isomerizaticn of 5-hexenyl radical, the absolute rate constants for free-radical addition to 1,4-benzcquincne was determined (ka = (2.0 + 0.7).107 M-1 sec-1 at 69°C).File in questo prodotto:
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