N-chloroalkylamines in the presence of reducing metal salts and protonated quinoxaline undergoes intramolecular hydrogen abstraction to delta-aminoalkyl radicals which add to the protonated quinoxaline affording 2- and 6-delta-aminoalkylquinoxalines depending on the acidity of the medium.
Homolytic δ-aminoadeltalkylation of protonated quinoxaline by N-chloroamine
Citterio, A.;GHIRARDINI, MAURIZIO;Minisci, F.
1976-01-01
Abstract
N-chloroalkylamines in the presence of reducing metal salts and protonated quinoxaline undergoes intramolecular hydrogen abstraction to delta-aminoalkyl radicals which add to the protonated quinoxaline affording 2- and 6-delta-aminoalkylquinoxalines depending on the acidity of the medium.File in questo prodotto:
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