N-chloroalkylamines in the presence of reducing metal salts and protonated quinoxaline undergoes intramolecular hydrogen abstraction to delta-aminoalkyl radicals which add to the protonated quinoxaline affording 2- and 6-delta-aminoalkylquinoxalines depending on the acidity of the medium.

Homolytic δ-aminoadeltalkylation of protonated quinoxaline by N-chloroamine

Citterio, A.;GHIRARDINI, MAURIZIO;Minisci, F.
1976-01-01

Abstract

N-chloroalkylamines in the presence of reducing metal salts and protonated quinoxaline undergoes intramolecular hydrogen abstraction to delta-aminoalkyl radicals which add to the protonated quinoxaline affording 2- and 6-delta-aminoalkylquinoxalines depending on the acidity of the medium.
1976
Organic Chemistry; Free radicals, quinoxaline, alkylation, N-chloroamines
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/1047377
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