Effect of synthetic route on performance of La0.8Sr1.2Fe0.9Cu0.1O4±δ electrodes for symmetric solid oxides fuel cells

The solid oxide La0.8Sr1.2Fe0.9Cu0.1O4±δ of interest as electrode for Symmetric Solid Oxide Fuel Cells (SSOFCs) has been prepared via three different synthetic methods: solid-state reaction (SSR), melt citrate route (MC) and co-precipitation (CoP). In order to determine advantages and drawbacks of each synthesis, the materials have been characterized by X-Ray Powder Diffraction (XRD) and Scanning Electron Microscopy (SEM) analysis. Phase purity, structural and morphological characteristics of the powders have been determined. Wet chemical methods (CIT and COP) have the advantage over SSR synthesis of yielding small-sized powders (∼1mu;m); moreover, melt citrate route allows lowering the preparation temperature down to 1000 °C. Electrochemical characterization was performed by Electrochemical Impedance Spectroscopy (EIS) in air in an electrolyte supported symmetric cells configuration. Preliminary results allow to draw some conclusions on the relation between the structural and microstructural characteristics of the powders and the electrochemical performance.