The preparation of uranium carbide (UC) by carbothermal reduction and its sintering into dense pellets by conventional means require high temperatures for long periods. We have developed a preparation route yielding fine UC powder with significantly increased sinterability. At first, a mixture of nanocrystalline UO2 embedded in amorphous carbon (nano-UO2/C) was obtained by thermal decomposition of a gel containing solubilised uranyl nitrate and citric acid. Later, the nano-UO2/C powder was treated in a conventional furnace or in a modified spark plasma sintering facility at elevated temperatures (≥1200°C) in order to obtain uranium carbide powder. The effects of initial composition, temperature, gas/vacuum atmosphere and the overall reaction kinetics are reported.
|Titolo:||Innovative preparation route for uranium carbide using citric acid as a carbon source|
|Autori interni:||LUZZI, LELIO|
|Data di pubblicazione:||2016|
|Appare nelle tipologie:||01.1 Articolo in Rivista|
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|Ceramics_International_42_(2016)_16710-16717.pdf||Articolo principale||2.34 MB||Adobe PDF||Post-print||Accesso riservato|