The reaction of I in H2SO4 in presence of Fe2+ salt leads to II and III. The product ratio, II/III, decreases with decreasing [H2SO4]. Two competitive processes involving the same amino radical cation intermediate (IV) explain the products. The chain producing II reproduces the Hoffman-Loeffler reaction
Chemistry of the amino radical ions. A new chain process of the protonated N-chloramines
AURICCHIO, SERGIO;CITTERIO, ATTILIO;MINISCI, FRANCESCO;
1984-01-01
Abstract
The reaction of I in H2SO4 in presence of Fe2+ salt leads to II and III. The product ratio, II/III, decreases with decreasing [H2SO4]. Two competitive processes involving the same amino radical cation intermediate (IV) explain the products. The chain producing II reproduces the Hoffman-Loeffler reactionFile in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
