A review with 13 refs. Radical reactions induced by monoelectronic redox metals proved useful in the synthesis of naphthols and dihydro- or tetrahydro-naphthalenes. Examples of either intra- or consecutive inter-intramol. oxidative radical alkylations of arom. are reported. The reactivity of carbon centered β-dicarbonyl, alkyl and vinyl radicals, generated in the presence of metallic salts Mn(III), Fe(III), Ce(IV), and the influence of the redox couple on the selectivity to the products are examd. The potentiality of the method is evidenced by the possibility to carry out such reactions in an electrocatalytic way with high yield

Stoichiometric and catalytic reactions of free radicals generated by metallic redox couples. Application to the synthesis of naphthalene derivatives

CITTERIO, ATTILIO
1993-01-01

Abstract

A review with 13 refs. Radical reactions induced by monoelectronic redox metals proved useful in the synthesis of naphthols and dihydro- or tetrahydro-naphthalenes. Examples of either intra- or consecutive inter-intramol. oxidative radical alkylations of arom. are reported. The reactivity of carbon centered β-dicarbonyl, alkyl and vinyl radicals, generated in the presence of metallic salts Mn(III), Fe(III), Ce(IV), and the influence of the redox couple on the selectivity to the products are examd. The potentiality of the method is evidenced by the possibility to carry out such reactions in an electrocatalytic way with high yield
1993
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11311/662383
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