Thecomplexes [M(eta-3-C4H7)(SnC13)(CO)] [C4H, = 2-methylallyl, M = Pt(1) or Pd(2)] have been prepared and characterized. Their solution behaviour has been studied by n.m.r. spectroscopy, the compounds being dynamic through dissociation of the CO ligand. The X-ray structures of (1 ) and (2) are reported. Complex (2) is the first mononuclear palladium carbonyl to be characterized by Xray diffraction. The different stabilities of the two isostructural complexes are correlated with the subtle differences in bonding observed in the crystal structures.
CRYSTALLOGRAPHIC AND NUCLEAR MAGNETIC-RESONANCE STUDIES OF CARBONYL (ETA-3-METHYLALLYL)(TRICHLOROSTANNYL) COMPLEXES OF PLATINUM(II) AND PALLADIUM(II)
MEILLE, STEFANO VALDO;
1989-01-01
Abstract
Thecomplexes [M(eta-3-C4H7)(SnC13)(CO)] [C4H, = 2-methylallyl, M = Pt(1) or Pd(2)] have been prepared and characterized. Their solution behaviour has been studied by n.m.r. spectroscopy, the compounds being dynamic through dissociation of the CO ligand. The X-ray structures of (1 ) and (2) are reported. Complex (2) is the first mononuclear palladium carbonyl to be characterized by Xray diffraction. The different stabilities of the two isostructural complexes are correlated with the subtle differences in bonding observed in the crystal structures.File in questo prodotto:
File | Dimensione | Formato | |
---|---|---|---|
pub026 Musco Pt(II)-Pd(II) CO SNCl3 compl.pdf
Accesso riservato
:
Post-Print (DRAFT o Author’s Accepted Manuscript-AAM)
Dimensione
731.96 kB
Formato
Adobe PDF
|
731.96 kB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.