optically pure α′-monofluoro-α-sulphinyl ketones have been reduced with high diastereoselection to give α′-fluoro-α-sulphinyl alcohols which upon removal of the sulphinyl residue produced enantiomerically pure fluorhydrins. Threo and erythro fluorhydrins if type are obtained in enantiomerically pure form through a highly diastereoselectivel reduction of α′-fluoro-α-sulphinyl ketones and successive removal of the sulphinyl group.
An efficient approach to enantiomerically pure fluorhydrins
BRAVO, PIERFRANCESCO;RESNATI, GIUSEPPE
1987-01-01
Abstract
optically pure α′-monofluoro-α-sulphinyl ketones have been reduced with high diastereoselection to give α′-fluoro-α-sulphinyl alcohols which upon removal of the sulphinyl residue produced enantiomerically pure fluorhydrins. Threo and erythro fluorhydrins if type are obtained in enantiomerically pure form through a highly diastereoselectivel reduction of α′-fluoro-α-sulphinyl ketones and successive removal of the sulphinyl group.File in questo prodotto:
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